Scientific American Supplement, No. 363, December 16, 1882

V >> Various >> Scientific American Supplement, No. 363, December 16, 1882

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In operating thus, all the remaining ammonia that might have escaped the
condenso-purifier is removed, and the result is obtained without pumps
or motor, with apparatus that costs but little and does not occupy much
space. The advantages that are derived from this, as regards sulphate
of ammonia, are important; for, on treating ammoniacal waters with
condensers, scarcely more than four to five kilogrammes of the sulphate
are obtained per ton of coal distilled, while by washing the gas
perfectly with the small quantity of water indicated, four to five
kilogrammes more can be got per 1,000 kilogrammes of coal, or a total of
eight to ten kilogrammes per ton.

When the gas is not washed sufficiently, almost all of the ammonia
condenses in the purifying material.

The pressure absorbed by the condenso purifier is from ten to twelve
millimeters per washing-diaphragm. In works that are not provided with
an extractor, two diaphragms, or even a single one, are employed when it
is desired simply to catch the tar.

The apparatus under consideration was employed in the St. Quentin
gas works during the winter of 1881-1882, without giving rise to any
obstruction; and, besides, it was found that by its use there might be
avoided all choking up of the pipes at the works and the city mains
through naphthaline.

In cases of obstruction, it is very easy to take out the perforated
diaphragms; this being done by removing the bolts from the piece that
holds the register, f, and then removing the diaphragm and putting in
another. This operation takes about ten minutes. The advantages of such
a mounting of the diaphragms is that it allows the gas manufacturer to
employ (and easily change) the number of perforations that he finds best
suited to his needs.

These apparatus are constructed for productions of from 1,000 to 100,000
cubic meters of gas per twenty four hours. They have been applied
advantageously in the washing of smoke from potassa furnaces, in order
to collect the ammonia that escapes from the chimneys. In one of such
applications, the quantity of gas and steam washed reached a million
cubic meters per twenty-four hours.--_Revue Industrielle._

* * * * *

ARTIFICIAL IVORY.

It is said that artificial ivory of a pure white color and very durable
has been manufactured by dissolving shellac in ammonia, mixing the
solution with oxide of zinc, driving off ammonia by heating, powdering,
and strongly compressing in moulds.

* * * * *

CREOSOTE IMPURITIES.

[Footnote: Read at the meeting of the American Pharmaceutical
Association held at Niagara Falls. 1882.]

By Prof. P. W. BEDFORD.

The object of this query can be but one, namely, to inquire whether the
wood creosote offered for sale is a pure article, or not; and if not,
what is the impurity present?

The relative commercial value of the articles sold as coal tar creosote
and wood creosote disposes of the question as to the latter being
present in the former article, and we are quite certain that the cheap
variety is nothing more or less than a phenol or carbolic acid. Wood
creosote, it has been frequently stated, is adulterated with coal tar
creosote, or phenol. The object of my experiments has been to prove the
identity of wood creosote and its freedom from phenol. The following
tests are laid down in various works as conclusive evidence of its
purity, and each has been fully tried with the several samples of wood
creosote to prove their identity and purity, and also with phenol, sold
as commercial creosote or coal tar creosote, and for comparison with
mixtures of the two, that even small percentages of admixture might be
identified, should such exist in the wood creosote of the market.

The following tests were used:

1. Equal volumes of anhydrous glycerine and wood creosote make a turbid
mixture, separating on standing. _Phenol dissolves_. If three volumes
of water be added, the separation of the wood creosote is immediate.
_Phenol remains in permanent solution_.

2. One volume of wood creosote added to two volumes of glycerine; the
former is not dissolved, but separates on standing. _Phenol dissolves_.

3. Three parts of a mixture containing 75 per cent, of glycerine and
25 of water to 1 part of wood creosote show no increase of volume of
glycerine, and wood creosote separates. _Phenol dissolves, and forms
a clear mixture_. Were any phenol present in the wood creosote, the
increase in the volume of the glycerine solution, if in a graduated
tube, would distinctly indicate the percentage of phenol present.

4. Solubility in benzine. Wood creosote entirely soluble. _Phenol is
insoluble_.

5. A 1 per cent, solution of wood creosote. Take of this 10 cubic
centimeters, add 1 drop of a test solution of ferric chloride; an
evanescent blue color is formed, passing quickly into a red color.
_Phenol gives a permanent blue color_.

6. Collodion or albumen with an equal bulk of wood creosote makes a
perfect mixture without coagulation. _Phenol at once coagulates into a
more or less firm mass or clot_.

7. Bromine solution with wood creosote gives a reddish brown
precipitate. _Phenol gives a white precipitate_.

All tests enumerated above were repeatedly tried with four samples of
wood creosote sold as such; one a sample of Morson's, one of Merck's,
one evidently of German origin, but bearing the label and capsule of an
American manufacturer, and one of unknown origin, but sold as beech-wood
creosote (German), and each proved to be _pure wood creosote_.

Two samples of commercial creosote which, from the low cost, were known
to be of coal tar origin gave the negative tests, showing that they were
phenol.

Corroborative experiments were made by mixing 10 to 20 per cent, of
phenol with samples of the beechwood creosote, but in every case each of
the tests named showed the presence of the phenol.

The writer on other occasions applied single tests (the collodion test)
to samples of beechwood creosote that he had an opportunity of procuring
small specimens of, and satisfied himself that they were pure. The
conclusion is that the wood creosote of the market of the present time
is in abundant supply, is of unexceptionable quality, and reasonable in
price, so that there is no excuse for the substitution of the phenol
commonly sold for it. When it is directed for use for internal
administration (the medicinal effect being entirely dissimilar), wood
creosote only should be dispensed.

The general sales of creosote by the pharmacist are in small quantities
as a toothache remedy, and phenol has the power of coagulating albumen,
which effectually relieves the suffering. Wood creosote does not
coagulate albumen, and is, therefore, not as serviceable. This is,
perhaps, the reason that it has become, in a great measure, supplanted
in general sale by the coal tar creosote, to say nothing of the argument
of a lower cost.

* * * * *

REMEDY FOR SICK HEADACHE.

Surgeon Major Roehring, of Amberg, reports, in No. 32 of the _Allg. Med.
Centr. Zeit_., April 22, 1882, a case of headache of long standing,
which he cured by salicylate of sodium, which confirms the observations
of Dr. Oehlschlager, of Dantzig, who first contended that we possessed
in salicylic acid one of the most reliable remedies for neuralgia. This
cannot astonish us if we remember that the action of salicylic acid is,
in more than one respect, and especially in its influence on the nervous
centers, analogous to quinine.

While out with the troops on maneuver, Dr. Roehring was called to visit
the sixteen-year old son of a poor peasant family in a neighboring
village. The boy, who gave all evidences of living under bad hygienic
surroundings, but who had shown himself very diligent at school, had
been suffering, from his sixth year, several days every week from the
most intense headache, which had not been relieved by any of the many
remedies tried for this purpose. A careful examination did not reveal
any organic lesion or any cause for the pain, which seemed to be
neuralgic in character, a purely nervous headache. Roehring had just
been reading the observations of Oehlschlager, and knowing, from the
names of the physicians who had been already attending the poor boy,
that all the common remedies for neuralgia had been given a fair trial,
thought this a good opportunity to test the virtue of salicylate of
sodium. He gave the boy, who, in consequence of the severity of the
pain, was not able to leave his bed, ten grains of the remedy every
three hours, and was surprised to see the patient next day in his tent
and with smiling face. The boy admitted that he for years had not been
feeling so well as he did then. The remedy was continued, but in less
frequent doses, for a few days longer; the headache did not return.
Several months later Dr. Roehring wrote to the school-teacher of the
boy, and was informed that the latter had, during all this time,
been totally free of his former pain, that he was much brighter than
formerly, and evidently enjoying the best of health.

It may be worth while to give the remedy a more extensive trial, and the
more so as we are only too often at a loss what to do in stubborn cases
of so-called nervous headache.--_The Medical and Surgical Reporter_.

* * * * *

SUNLIGHT AND SKYLIGHT AT HIGH ALTITUDES.

At the Southampton meeting of the British Association, Captain Abney
read a paper in which he called attention to the fact that photographs
taken at high altitudes show skies that are nearly black by comparison
with bright objects projected against them, and he went on to show that
the higher above the sea level the observer went, the darker the sky
really is and the fainter the spectrum. In fact, the latter shows but
little more than a band in the violet and ultraviolet at a height of
8,500 feet, while at sea-level it shows nearly the whole photographic
spectrum. The only reason of this must be particles of some reflecting
matter from which sunlight is reflected. The author refers this to
watery stuff, of which nine-tenths is left behind at the altitude at
which be worked. He then showed that the brightness of the ultra-violet
of direct sunlight increased enormously the higher the observer went,
but only to a certain point, for the spectrum suddenly terminated about
2,940 wave-length. This abrupt absorption was due to extra-atmospheric
causes and perhaps to space. The increase in brightness of the
ultra-violet was such that the usually invisible rays, L, M, N, could be
distinctly seen, showing that the visibility of these rays depended
on the intensity of the radiation. The red and ultra-red part of the
spectrum was also considered. He showed that the absorption lines were
present in undiminished force and number at this high altitude, thus
placing their origin to extra-atmospheric causes. The absorption from
atmospheric causes of radiant enemy in these parts he showed was due
to "water-stuff," which he hesitated to call aqueous vapor, since the
banded spectrum of water was present, and not lines. The B and A line he
also stated could not be claimed as telluric lines, much less as due to
aqueous vapor, but must originate between the sun and our atmosphere.
The author finally confirmed the presence of benzine and ethyl in the
same region. He had found their presence indicated in the spectrum at
sea-level, and found their absorption lines with undiminished intensity
at 8,500 feet. Thus, without much doubt, hydrocarbons must exist between
our atmosphere and the sun, and, it may be, in space.

Prof. Langley, following Capt. Abney, observed: The very remarkable
paper just read by Captain Abney has already brought information
upon some points which the one I am about, by the courtesy of the
Association, to present, leaves in doubt. It will be understood then
that the references here are to his published memoirs only, and not to
what we have just heard.

The solar spectrum is so commonly composed to have been mapped with
completeness, that the statement that much more than one-half its extent
is not only unmapped but nearly unknown, may excite surprise. This
statement is, however, I think, quite within the truth, as to that
almost unexplored region discovered by the elder Herschel, which, lying
below the red and invisible to the eye, is so compressed by the prism
that, though its aggregate heat effects have been studied through the
thermopile, it is only by the recent researches of Capt. Abney that we
have any certain knowledge of the lines of absorption there, even in
part. Though the last-named investigator has extended our knowledge of
it to a point much beyond the lowest visible ray, there yet remains a
still remoter region, more extensive than the whole visible spectrum,
the study of which has been entered on at Alleghany, by means of the
linear bolometer.

The whole spectrum, visible and invisible, is powerfully affected by the
selective absorption of our atmosphere and that of the sun; and we must
first observe that could we get outside our earth's atmospheric shell,
we should see a second and very different spectrum, and could we
afterward remove the solar atmosphere also, we should have yet a third,
different from either. The charts exhibited show:

1st. The distribution of the solar energy as we receive it, at the
earth's surface, throughout the entire invisible as well as visible
portion, both on the prismatic and normal scales. This is what I have
principally to speak of now, but this whole first research is but
incidental to others upon the spectra before any absorption, which
though incomplete, I wish to briefly allude to later. The other curves
then indicate:

2d. The distribution of energy before absorption by our own atmosphere.

3d. This distribution at the photosphere of the sun. The extent of
the field, newly studied, is shown by this drawing [chart exhibited].
Between H in the extreme violet, and A in the furthest red, lies the
visible spectrum, with which we are familiar, its length being about
4,000 of Angstrom's units. If, then, 4,000 represent the length of the
visible spectrum, the chart shows that the region below extends through
24,000 more, and so much of this as lies below wave-length 12,000, I
think, is now mapped for the first time.

[Illustration: FIG. 1.--PRISMATIC SPECTRUM.]

We have to pi = 12,000 relatively complete photographs, published by
Capt. Abney, but, except some very slight indications by Lamansky,
Desains, and Mouton, no further guide.

Deviations being proportionate to abscissae, and measured solar energies
to ordinates, we have here (1) the distribution of energy in the
prismatic, and (2) its distribution in the normal spectrum. The total
energy is in each case proportionate to the area of the curve (the two
very dissimilar curves inclosing the same area), and on each, if the
total energy be roughly divided into four parts, one of these will
correspond to the visible, and three to the invisible or ultra-red part.
The total energy at the ultra violet end is so small, then, as to be
here altogether negligible.

We observe that (owing to the distortion introduced by the prism) the
maximum ordinate representing the heat in the prismatic spectrum is, as
observed by Tyndall, below the red, while upon the normal scale this
maximum ordinate is found in the orange.

I would next ask your attention to the fact that in either spectrum,
below pi = 12,000 are most extraordinary depressions and interruptions
of the energy, to which, as will be seen, the visible spectrum offers
no parallel. As to the agent producing these great gaps, which so
strikingly interrupt the continuity of the curve, and, as you see,
in one place, cut it completely into two, I have as yet obtained no
conclusive evidence. Knowing the great absorption of water vapor in this
lowest region, as we already do, from the observations of Tyndall, it
would, _a priori_, seem not unreasonable to look to it as the cause. On
the other hand, when I have continued observations from noon to sunset,
making successive measures of each ordinate, as the sinking sun sent its
rays through greater depths of absorbing atmosphere, I have not found
these gaps increasing as much as they apparently should, if due to a
terrestrial cause, and so far as this evidence goes, they might be
rather thought to be solar. But my own means of investigation are not so
well adapted to decide this important point as those of photography, to
which we may yet be indebted for our final conclusion.

[Illustration: FIG. 2.--NORMAL SPECTRUM. (At sea level.)]

I am led, from a study of Capt. Abney's photographs of the region
between pi = 8,000 and pi = 12,000, to think that these gaps are
produced by the aggregation of finer lines, which can best be
discriminated by the camera, an instrument which, where it can be used
at all, is far more sensitive than the bolometer; while the latter, I
think, has on the other hand some advantage in affording direct and
trustworthy measures of the amount of energy inhering in each ray.

One reason why the extent of this great region has been so singularly
underestimated, is the deceptively small space into which it appears to
be compressed by the distortion of the prism. To discriminate between
these crowded rays, I have been driven to the invention of a special
instrument. The bolometer, which I have here, is an instrument depending
upon principles which I need not explain at length, since all present
may be presumed to be familiar with the success which has before
attended their application in another field in the hands of the
President of this Association.

I may remark, however, that this special construction has involved very
considerable difficulties and long labor. For the instrument here shown,
platinum has been rolled by Messrs. Tiffany, of New York, into sheets,
which, as determined by the kindness of Professor Rood, reach the
surprising tenuity of less than one twenty-five-thousandth of an English
inch (I have also iron rolled to one fifteen-thousandth inch), and from
this platinum a strip is cut one one-hundred-and-twenty-fifth of an inch
wide. This minute strip, forming one arm of a Wheatstone's bridge, and
thus perfectly shielded from air currents, is accurately centered by
means of a compound microscope in this truly turned cylinder, and the
cylinder itself is exactly directed by the arms of this Y.

The attached galvanometer responds readily to changes of temperature, of
much less than one-ten-thousandth degree F. Since it is one and the same
solar energy whose manifestations we call "light" or "heat," according
to the medium which interprets them, what is "light" to the eye is
"heat" to the bolometer, and what is seen as a dark line by the eye is
felt as a cold line by the sentient instrument. Accordingly, if lines
analogous to the dark "Fraunhofer lines" exist in this invisible region,
they will appear (if I may so speak) to the bolometer as cold bands, and
this hair-like strip of platina is moved along in the invisible part of
the spectrum till the galvanometer indicates the all but infinitesimal
change of temperature caused by its contact with such a "cold band." The
whole work, it will be seen, is necessarily very slow; it is in fact a
long groping in the dark, and it demands extreme patience. A portion of
its results are now before you.

The most tedious part of the whole process has been the determination of
the wave-lengths. It will be remembered that we have (except through the
work of Capt. Abney already cited, and perhaps of M. Mouton) no direct
knowledge of the wave-lengths in the infra-red prismatic spectrum, but
have hitherto inferred them from formulas like the well-known one of
Cauchy's, all which known to me appear to be here found erroneous by the
test of direct experiment, at least in the case of the prism actually
employed.

I have been greatly aided in this part of the work by the remarkable
concave gratings lately constructed by Prof. Rowland, of Baltimore, one
of which I have the pleasure of showing you. [Instrument exhibited.]

The spectra formed by this fall upon a screen in which is a fine slit,
only permitting nearly homogeneous rays to pass, and these, which may
contain the rays of as many as four overlapping spectra, are next passed
through a rock-salt or glass prism placed with its refracting edge
parallel to the grating lines. This sorts out the different narrow
spectral images, without danger of overlapping, and after their passage
through the prism we find them again, and fix their position by means of
the bolometer, which for this purpose is attached to a special kind of
spectrometer, where its platinum thread replaces the reticule of the
ordinary telescope. This is very difficult work, especially in the
lowermost spectrum, where I have spent over two weeks of consecutive
labor in fixing a single wave-length.

The final result is, I think, worth, the trouble, however, for, as you
see here, we are now able to fix with approximate precision and by
direct experiment, the wave-length of every prismatic spectral ray. The
terminal ray of the solar spectrum, whose presence has been certainly
felt by the bolometer, has a wave-length of about 28,000 (or is nearly
two octaves below the "great A" of Fraunhofer).

So far, it appears only that we have been measuring _heat_, but I
have called the curve that of solar "energy," because by a series of
independent investigations, not here given, the selective absorption
of the silver, the speculum-metal, the glass, and the lamp-black
(the latter used on the bolometer-strip), forming the agents of
investigation, has been separately allowed for. My study of lamp-black
absorption, I should add in qualification, is not quite complete. I have
found it quite transparent to certain infra-red rays, and it is very
possible that there may be some faint radiations yet to be discovered
even below those here indicated.

In view of the increased attention that is doubtless soon to be given
to this most interesting but strangely neglected region, and which by
photography and other methods is certain to be fully mapped hereafter, I
can but consider this present work less as a survey than as a sketch of
this great new field, and it is as such only that I here present it.

All that has preceded is subordinate to the main research, on which I
have occupied the past two years at Alleghany, in comparing the spectra
of the sun at high and low altitudes, but which I must here touch upon
briefly. By the generosity of a friend of the Alleghany Observatory, and
by the aid of Gen. Hazen, Chief Signal Officer of the U S. Army, I was
enabled last year to organize an expedition to Mount Whitney in South
California, where the most important of these latter observations were
repeated at an altitude of 13,000 feet. Upon my return I made a special
investigation upon the selective absorption of the sun's atmosphere,
with results which I can now only allude to.

By such observations, but by methods too elaborate for present
description, we can pass from the curve of energy actually observed to
that which would be seen if the observer were stationed wholly above the
earth's atmosphere, and freed from the effect of its absorption.

The salient and remarkable result is the growth of the blue end of the
spectrum, and I would remark that, while it has been long known from
the researches of Lockyer, Crova, and others that certain rays of short
wave-length were more absorbed than those of long, these charts show
_how much_ separate each ray of the spectrum has grown, and bring, what
seems to me, conclusive evidence of the shifting of the point of maximum
energy without the atmosphere toward the blue. Contrary to the accepted
belief, it appears here also that the absorption on the whole grows less
and less, to the extreme infra-red extremity; and on the other hand,
that the energy before absorption was so enormously greater in the blue
and violet, that the sun must have a decidedly bluish tint to the naked
eye, if we could rise above the earth's atmosphere to view it.

But even were we placed outside the earth's atmosphere, that surrounding
the sun itself would still remain, and exert absorption. By special
methods, not here detailed, we have at Alleghany compared the
absorption, at various depths, of the sun's own atmosphere for each
spectral ray, and are hence enabled to show, with approximate truth, I
think for the first time, the original distribution of energy throughout
the visible and invisible spectrum at the fount of that energy, in the
sun itself. There is a surprising similarity, you will notice, in the
character of the solar and telluric absorptions, and one which we could
hardly have anticipated _a priori_.

Here, too, violet has been absorbed enormously more than the green, and
the green than the red, and so on, the difference being so great, that
if we were to calculate the thickness of the solar atmosphere on the
hypothesis of a uniform transmission, we should obtain a very thick
atmosphere from the rate of absorption in the infra-red alone, and a
very thin one from that in the violet alone.

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